Nick had two different roles in THE X-FILES: a guest appearance as Michael in the first season, and a recurring role as Agent Alex Krycek from the second season on. He's been in 24 episodes so far (25 if you count "Inside THE X-FILES").
Alphabetical Listing of Nick's Episodes:
"Anasazi" (#2.25, May 19, 1995)
"Apocrypha" (#3.16, February 16, 1996)
"Ascension" (#2.6, October 21, 1994)
"Biogenesis" (#6.22, May 16, 1999)
"The Blessing Way" (#3.1, September 22, 1995)
"Deadalive" (#8.15, April 1, 2001)
"Duane Barry" (#2.5, October 14, 1994)
"The End" (#5.20, May 17, 1998)
"Essence" (#8.20, May 13, 2001)
"Existence" (#8.21, May 20, 2001)
"Genderbender" (#1.13, January 21, 1994) [as "Michael"]
"Inside THE X-FILES" (February 1, 1998)
"One Son" (#6.12, February 14, 1999)
"Paper Clip" (#3.2, September 29, 1995)
"Patient X" (#5.13, March 1, 1998)
"Piper Maru" (#3.15, February 9, 1996)
"The Red and the Black" (#5.14, March 8, 1998)
"Requiem" (#7.22, May 21, 2000)
"The Sixth Extinction II: Amor Fati" (#7.2, November 14, 1999)
"Sleepless" (#2.4, October 7, 1994)
"S.R. 819" (#6.10, January 17, 1999)
"Terma" (#4.10, December 1, 1996)
"The Truth" (#9.20, May 19, 2002)
"Tunguska" (#4.9, November 24, 1996)
"Two Fathers" (#6.11, February 7, 1999)
Chronological Listing of Nick's Episodes:
"Genderbender" (#1.13, January 21, 1994) [as "Michael"]
"Sleepless" (#2.4, October 7, 1994)
"Duane Barry" (#2.5, October 14, 1994)
"Ascension" (#2.6, October 21, 1994)
"Anasazi," (#2.25, May 19, 1995)
"The Blessing Way" (#3.1, September 22, 1995)
"Paper Clip" (#3.2, September 29, 1995)
"Piper Maru" (#3.15, February 9, 1996)
"Apocrypha" (#3.16, February 16, 1996)
"Tunguska" (#4.9, November 24, 1996)
"Terma" (#4.10, December 1, 1996)
"Inside THE X-FILES" (February 1, 1998)
"Patient X" (#5.13, March 1, 1998)
"The Red and the Black" (#5.14, March 8, 1998)
"The End" (#5.20, May 17, 1998)
"S.R. 819" (#6.10, January 17, 1999)
"Two Fathers" (#6.11, February 7, 1999)
"One Son" (#6.12, February 14, 1999)
"Biogenesis" (#6.22, May 16, 1999)
"The Sixth Extinction II: Amor Fati" (#7.2, November 14, 1999)
"Requiem" (#7.22, May 21, 2000)
"Deadalive" (#8.15, April 1, 2001)
"Essence" (#8.20, May 13, 2001)
"Existence" (#8.21, May 20, 2001)
"The Truth" (#9.20, May 19, 2002)